Method and apparatus for characterizing inorganic scale formation conditions employing a microfludic device

ABSTRACT

A test method and apparatus employs a microfluidic device to characterize properties of a fluid. The microfluidic device has an inlet port, an outlet port, and a microchannel as part of a fluid path between the inlet port and the outlet port. While a fluid is introduced into the microchannel, the fluid temperature is maintained while the fluid pressure in the microchannel is varied to characterize the properties of the fluid in the microchannel. The properties of the fluid can relate to a scale onset condition of the fluid at the pressure of the flow through the microchannel. In one aspect, fluid pressure in the microchannel is maintained while the fluid temperature is varied to characterize the properties of the fluid. In another aspect, flow rate of the fluid through the microchannel is varied while the fluid temperature is maintained to characterize the properties of the fluid in the microchannel.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a divisional of U.S. patent application Ser. No.15/503305, filed Aug. 11, 2014 and entitled “METHOD AND APPARATUS FORCHARACTERIZING INORGANIC SCALE FORMATION CONDITIONS EMPLOYING AMICROFLUIDIC DEVICE” which is incorporated herein by reference in itsentirety.

BACKGROUND Field

The present application relates to the detection of the formation ofinorganic scale and in particular, but not exclusively, to themeasurement of pressures and corresponding temperatures at whichinorganic scale is found to form.

Related Art

Inorganic scale (or scale) is a deposit or coating formed on the surfaceof metal, rock, or other material. Scale can be caused by precipitationdue to a chemical reaction with the surface of such materials, byprecipitation caused by chemical reactions in the fluid, by a change inpressure or temperature, and by a change in the composition of thefluid. Common scales are calcium carbonate, calcium sulfate, bariumsulfate, strontium sulfate, iron sulfide, iron oxides, iron carbonate,the various silicates and phosphates and oxides, or any of a number ofcompounds insoluble or slightly soluble in water.

Scale formation is of interest in the petroleum industry, particularlywith respect to producing, transporting, and processing of natural gasand petroleum fluids. In the case of oil and gas wells, scale may occuron wellbore tubulars and components as the saturation of produced wateris affected by changing temperature and pressure conditions in theproduction conduit. In severe conditions, scale creates a significantrestriction, or even a plug, in the wellbore tubulars. For example,damage due to inorganic scale formation in a well, formation, orreservoir during water injection at high pressure and high temperature(HPHT) conditions is a challenge to the petroleum industry. Scaleremoval is a common well intervention operation, with a wide range ofmechanical, chemical, and scale inhibitor treatment options available.However, remediation and cleaning of water scales costs the petroleumindustry millions of dollars each year.

At present, no standard laboratory test is available to accuratelydetect and measure the scale onset condition at reservoir conditions(which is often at high pressure and high temperature). Although, thethermodynamic models for scale prediction are well known and reliable,these models require very accurate composition of the water samples atreservoir conditions as primary input. However, acquiring arepresentative sample of the formation water to measure composition witha high degree of accuracy is a significant challenge; specifically whenthe sample must be transported to the laboratory in a pressurizedcontainer. Quite often the sample integrity is compromised due tochanges in pressure and temperature as well as compositional variationduring transportation. Hence, it is important to measure the scaleformation condition of the sample immediately after the sample iscollected, for example at the wellsite.

SUMMARY

This summary is provided to introduce a selection of concepts that arefurther described below in the detailed description. This summary is notintended to identify key or essential features of the claimed subjectmatter, nor is it intended to be used as an aid in limiting the scope ofthe claimed subject matter.

Illustrative embodiments of the present disclosure are directed to atest method and a test apparatus that employs a microfluidic device tocharacterize properties of a fluid. The test method and apparatus areuseful in studying the effects of different formation injectionadditives on the particular reservoir fluid for different flow pressuresand/or additive concentrations as desired. Such operations can be usedto optimize a strategy for reservoir fluid production and/ortransportation that minimizes the formation of scale during theseprocesses.

In a first aspect, a test method is described for characterizingproperties of a fluid. A microfluidic device is provided having at leastan inlet port, an outlet port, and a microchannel as part of a fluidpath between the inlet port and the outlet port. The fluid is introducedinto the microchannel and the fluid is maintained at a constanttemperature in the microchannel. The fluid is evaluated while thepressure of the fluid in the microchannel is adjusted. A property of thefluid in the microchannel is characterized based on the evaluation ofthe fluid. The property of the fluid may relate to a scale onsetpressure, which is the pressure of the fluid when scale begins to form.The adjustment of the pressure, the evaluation of the fluid, and thefluid characterization may be repeated until a scale onset formationcondition occurs.

Also, in one embodiment, images of the fluid in the microchannel may becaptured. The evaluation of the fluid may include an analysis of thecaptured images in order to determine whether such images includeinformation that indicates the presence of scale formation in the fluidin the microchannel.

In a second aspect, a test method is described for characterizingproperties of a fluid. A microfluidic device is provided having at leastan inlet port, an outlet port, and a microchannel as part of a fluidpath between the inlet port and the outlet port. A flow of the fluid isgenerated through the microchannel at a variable flow rate and atemperature of the fluid flowing through the microchannel is maintained.A pressure difference of the fluid across the microchannel and anaverage pressure of the fluid between an inlet and an outlet of themicrochannel are measured and recorded. The pressure difference isevaluated or analyzed while the flow rate is varied to determine whetherthe fluid in the microchannel flowing through the microchannel exhibitscharacteristics indicative of the presence of scale formation.

In one embodiment, the evaluation or analysis of the pressure differenceincludes determining if the pressure difference varies linearly with theflow rate, wherein, if it is determined that the pressure differencevaries linearly with the flow rate, then it is further determined thatthe fluid in the microchannel does not exhibit characteristicsindicative of the presence of scale formation, and if it is determinedthat the pressure difference varies non-linearly with the flow rate,then it is further determined that the fluid in the microchannel doesexhibit characteristics indicative of the presence of scale formation.

In one embodiment, scale onset pressure is identified as the averagepressure recorded at a transition point where the pressure differencetransitions between varying linearly and non-linearly with the flow rateand between varying non-linearly and linearly with the flow rate. Thefluid includes at least one of a reservoir fluid, a scale inhibitor,water, and a gas.

According to a third aspect, a test apparatus is described forcharacterizing properties of a fluid. The apparatus includes amicrofluidic device having at least an inlet port, an outlet port, and amicrochannel as part of a fluid path between the inlet port and theoutlet port. The apparatus also includes a temperature-controlledsurface that is thermally-coupled to the microfluidic device andconfigured to maintain a temperature of the microchannel of themicrofluidic device. Also, the apparatus includes at least onetemperature sensor for measuring a temperature characteristic of themicrochannel of the microfluidic device. Further the apparatus includesmeans for introducing the fluid into the microchannel, and a pressuresensor configured to measure pressure of the fluid in the microchannel.In addition, the apparatus includes means for adjusting the pressure ofthe fluid in the microchannel while the temperature characteristic ismaintained for evaluation of the fluid while the pressure is adjusted tocharacterize properties of the fluid in the microchannel based on theevaluation of the fluid.

In one embodiment, the apparatus includes a light source and cameraconfigured to capture images of the microchannel of the microfluidicdevice and fluid in the microchannel. Also, in one embodiment, the testapparatus includes means for evaluating or analyzing the images capturedby the camera in order to determine whether such images includeinformation that indicates the presence of scale formation in the fluidthat flows through the microchannel of the microfluidic device at arespective adjusted pressure. The means for adjusting the fluid pressureis constructed to iteratively adjust the fluid pressure and the meansfor evaluating or analyzing the images is constructed to iterativelyevaluate the images captured by the camera of the fluid in themicrochannel corresponding to each iterative adjustment of the fluidpressure.

In a fourth aspect, a test apparatus is described for characterizingproperties of a fluid. The apparatus includes a microfluidic devicehaving at least an inlet port, an outlet port, and a microchannel aspart of a fluid path between the inlet port and the outlet port. Theapparatus includes means for generating a flow of the fluid through themicrochannel at a variable flow rate. Also, the apparatus includes atemperature-controlled surface that is thermally-coupled to themicrofluidic device and configured to maintain a temperature of themicrochannel of the microfluidic device. The apparatus includes an inletpressure sensor configured to measure an inlet pressure of the fluid atthe inlet of the microchannel, and an outlet pressure sensor configuredto measure an outlet pressure of the fluid at the outlet of themicrochannel. Further, the apparatus includes measurement and recordingmeans for measuring and recording a pressure difference between theinlet and outlet pressures and measuring and recording an average of theinlet and outlet pressures. In addition, the apparatus includes meansfor evaluating or analyzing the pressure difference while the flow rateis varied to determine whether the fluid in the microchannel flowingthrough the microchannel exhibits characteristics indicative of thepresence of scale formation.

In one embodiment, the means for evaluating or analyzing determine ifthe pressure difference varies linearly with the flow rate, wherein, ifit is determined that the pressure difference varies linearly with theflow rate, then it is further determined that the fluid in themicrochannel does not exhibit characteristics indicative of the presenceof scale formation, and if it is determined that the pressure differencevaries non-linearly with the flow rate, then it is further determinedthat the fluid in the microchannel does exhibit characteristicsindicative of the presence of scale formation. Also, in one embodiment,the means for evaluating or analyzing identify a scale onset pressure,where scale begins to form, as the average pressure recorded at atransition point where the pressure difference transitions betweenvarying linearly and non-linearly with the flow rate and between varyingnon-linearly and linearly with the flow rate.

In a fifth aspect, a test method is described for characterizingproperties of a fluid. A microfluidic device is provided having at leastan inlet port, an outlet port, and a microchannel as part of a fluidpath between the inlet port and the outlet port. The fluid is introducedinto the microchannel and the fluid in the microchannel is maintained ata constant pressure. The pressure and temperature of the fluid in themicrochannel are measured and recorded. Properties of the fluid in themicrochannel are characterized based on evaluation of the fluid whilethe temperature of the fluid in the microchannel is adjusted. Theproperties of the fluid may relate to the scale onset temperature, whichis the temperature when scale begins to form. The adjustment of thetemperature, the evaluation of the fluid, and the characterization ofthe properties of the fluid may be repeated until the scale onsetformation condition occurs.

In one embodiment, images of the fluid in the microchannel are captured.Evaluation of the fluid may include an analysis of the captured imagesin order to determine whether such images include information thatindicates the presence of scale formation in the fluid in themicrochannel.

In a sixth aspect, a test apparatus is described for characterizingproperties of a fluid. The apparatus includes a microfluidic devicehaving at least an inlet port, an outlet port, and a microchannel aspart of a fluid path between the inlet port and the outlet port. Theapparatus includes means for introducing the fluid into themicrochannel, means for maintaining a constant pressure of the fluid inthe microchannel, and a temperature-controlled surface that isthermally-coupled to the microfluidic device and configured to adjust atemperature of the microchannel of the microfluidic device. Also, theapparatus includes a pressure sensor configured to measure the pressureof fluid in the microchannel, a temperature sensor constructed tomeasure the temperature of fluid in the microchannel, and means forevaluating properties of the fluid while the temperature of the fluid isadjusted. In one embodiment, properties of the fluid relate to scaleonset temperature.

Also, in one embodiment, the test apparatus can include a light sourceand camera configured to capture images of the microchannel of themicrofluidic device and fluid in the microchannel. Further, the testapparatus may include means for characterizing properties of the fluidin the microchannel based on the evaluation of the fluid, the meansconstructed to determine, responsive to analyzing the captured images,whether the images include information that indicates the presence ofscale formation in the fluid in the microchannel.

The fluid introduced into the microchannel can include at least one of areservoir fluid, a scale inhibitor, a water-based fluid (such asseawater, freshwater, or steam), and a gas.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic diagram of a test apparatus according to anembodiment of the present disclosure.

FIG. 2 is a schematic top view of another embodiment of a microfluidicdevice that can be used as part of the test apparatus of FIG. 1.

FIG. 3 is a schematic cross-sectional view of an embodiment of themicrofluidic device of FIG. 1 or FIG. 2 in conjunction with atemperature-controlled heating-cooling surface that is placed in thermalcontact with the microfluidic device.

FIG. 4 is a schematic diagram showing scale deposited inside themicrochannel of the microfluidic device of FIG. 1 during operation ofthe test apparatus.

FIG. 5 is a flow chart describing a sequence of test operations carriedout by the test apparatus of FIG. 1 to characterize properties relatedto scale onset formation conditions of fluid that flows through themicrochannel of the microfluidic device.

FIG. 6 is a flow chart describing a sequence of test operations carriedout by the test apparatus of FIG. 1 to characterize properties relatedto scale onset formation conditions of fluid that flows through themicrochannel of the microfluidic device.

FIG. 7 is a flow chart describing another sequence of test operationscarried out by the test apparatus of FIG. 1 to characterize propertiesrelated to scale onset formation conditions of fluid that flows throughthe microchannel of the microfluidic device.

FIG. 8 is a schematic diagram of a test apparatus according to anembodiment of the present disclosure, where a fluid that includes areservoir fluid component and possibly an additive flows through themicrochannel of the microfluidic device during operation of the testapparatus. In this case, the test apparatus can be used to characterizeproperties related to scale onset formation conditions of the fluid thatflows through the microchannel of the microfluidic device.

DETAILED DESCRIPTION

Illustrative embodiments of the present disclosure are described below.In the interest of clarity, not all features of an actual implementationare described in this specification. It will be appreciated that in thedevelopment of any such actual embodiment numerousimplementation-specific decisions must be made to achieve thedeveloper's specific goals, such as compliance with system-related andbusiness-related constraints, which will vary from one implementation toanother. Moreover, it will be appreciated that such a development effortmight be complex and time-consuming but would nevertheless be a routineundertaking for those of ordinary skill in the art having the benefit ofthis disclosure. Further, like reference numbers and designations in thevarious drawings indicate like elements.

For the purposes of this disclosure, the term “reservoir fluid” means afluid stored in or transmitted from a subsurface body of permeable rock.Thus “reservoir fluid” may include, without limitation, hydrocarbonfluids, saline fluids such as saline water, as well as other formationwater, and other fluids such as carbon dioxide in a supercritical phase.

Moreover, for the purposes of this disclosure, the term “microfluidicdevice” means a device having a fluid-carrying channel exhibiting awidth within a range of tens to hundreds of micrometers, but exhibitinga length that is many times longer than the width of the channel.Similarly the term “microchannel” means a fluid-carrying channelexhibiting a width within a range of tens to hundreds of micrometers.Although many of the microchannels described herein are of rectangularcross-section due to the practicalities of fabrication techniques, thecross-section of a microchannel can be of any shape, including round,oval, ellipsoid, square, etc.

A microfluidic device employs one or more microchannels (capillaries)where the surface area in contact with fluid flowing in the microchannelis relatively large compared to the volume of the fluid flowing throughthe microchannel. As a result, the heat transfer between the sample andits surroundings is rapid and the temperature of the fluid in themicrochannel can be changed rapidly. Also, due to the small dimensionsof the microchannel, the sample volume required in the microfluidicdevice amounts to a few micro-liters of liquid. For example, the size ofa microchannel's cross-section is on the order of the length scale ofreservoir pores (10 to 100 microns).

Therefore, the testing methods and apparatus described herein utilize amicrofluidic device for rapid and accurate detection of scale formed ina fluid sample flowing through the microfluidic device, the temperatureof which can be precisely controlled and maintained. The pressure-drivenflow of the fluid sample in the microfluidic device is monitored usingpressure sensors to identify properties of the scale formation condition(or the scale redissolution condition).

As shown in FIG. 1, a test apparatus 100 includes a microfluidic device101 that includes a first inlet port 103, a second inlet port 105, andan outlet port 107. The microfluidic device 101 also includes aninternal mixing section 109 (which can be a t-junction as shown) that isfluidly coupled to both the first inlet port 103 and the second inletport 105 as well as to a microchannel 111 that extends between themixing section 109 and the outlet port 107. The mixing section 109 canbe of various forms and shapes, such as the active and passive mixerscommonly used in microfluidic applications. The mixing section 109 canalso be external to the microfluidic device 101. In the embodiment shownin FIG. 1, the microchannel 111 can form a serpentine pattern, thusallowing the microchannel 111 to extend a significant length but occupya relatively small area. For example, the length of the serpentinepattern can be 1.7 meters. In another embodiment shown in FIG. 2, themicrochannel 111 can extend in a linear manner between the mixingsection 109 and the outlet port 107. In both the serpentine and straightmicrochannel configurations, the microchannel 111 has a uniformrectangular cross-section, which, in one embodiment, has a width ofabout 100 micrometers and a height of about 50 micrometers. However,other geometric shapes and dimensions could also be used. Themicrofluidic devices can be made from BOROFLOAT® glass (available fromSCHOTT North America, Inc. of Louisville, Ky., USA) and silicon usingstandard micro-fabrication processes.

In one embodiment shown in FIG. 3, the mixing section 109 and themicrochannel 111 of the microfluidic device 101 can be defined byetching the planar surface of a first substrate 122. The first substrate122 can be made of silicon (e.g., a conventional silicon-on-insulatorwafer) or other suitable material. A second substrate 153 can besealably bonded to the planar surface of the first substrate 122 thathas been etched to form the mixing section 109 and the microchannel 111.The bonding can employ an anodic bonding method after careful cleaningof the bonding surfaces of the first and second substrates 122, 153. Thefirst substrate 122 or the second substrate 153 can define the first andsecond inlet ports 103, 105 and the outlet port 107 that are in fluidcommunication with the mixing section 109 and the microchannel 111. Thesecond substrate 153 can be made of glass, such as borosilicate glass(such as BOROFLOAT® glass) or other suitable material. The flow paths ofthe mixing section 109 and the microchannel 111 can have uniformrectangular cross-sections formed in the first substrate as shown inFIG. 3. In one example, such rectangular cross-sections have a width (W)of 100 μm and a height (H) of 50 μm. However, the cross-sections canhave other geometric shapes as desired.

The microfluidic device 101 can be supported by (or otherwise thermallycoupled to) a temperature-controlled cooling/heating surface 135 thatprovides for temperature control of the microfluidic device 101(including the microchannel 111 therein) independent of the temperatureof the rest of the apparatus.

Turning back to FIG. 1, the test apparatus 100 also includes anelectrically-controlled reservoir and pump 113 that are loaded with aquantity of the reservoir fluid sample that contains one or morecomponents that can precipitate out as scale. The reservoir and pump 113have an outlet that is fluidly coupled to an electrically-controlledvalve 115. The reservoir and pump 113 and the valve 115 are operated tointroduce the reservoir fluid (for example, at or near a constant flowrate) into the first inlet port 103 of the microfluidic device 101. Apressure sensor 117 (such as the Sensotreme sensor available fromSensotreme GmbH of Ramsen, Switzerland) is disposed within the supplyline 119 between the valve 115 and the first inlet port 103 in order tomonitor the pressure of the fluid sample in the supply line 119. Thereservoir and pump 113 can be an electrically-controlled syringe pump,such as the ISCO 65D pump available from Teledyne Technologies Inc. ofLincoln, Nebr., USA. The supply line 119 can include an in-line filterthat removes particulate matter that could potentially clog themicrochannel 111 of the microfluidic device 101. The reservoir and pump113, the valve 115, and the supply line 119 can all operate at or nearambient temperature.

The test apparatus 100 also includes an electrically-controlledreservoir and pump 121 that are loaded with a quantity of liquid orpossibly a gas. The liquid or gas can be a water-based fluid (such asproduced water, flowback water, connate (formation) water,cross-linkers, gelling agents, fluid loss additives, thermalstabilizers, breakers, biocides, stabilizers, surfactants, claycontrollers, scale inhibitors, fracturing polymer solutions, seawater,fresh water, steam, injection gas, brine solution as completion fluid,or fracturing fluid which may be acid-based fluids or multiphase fluids(emulsions, foams, energized)) that can be used to stimulate productionof the reservoir fluid loaded into the reservoir and pump 113. Thereservoir and pump 121 have an outlet that is fluidly coupled to anelectrically-controlled valve 123. The reservoir and pump 121 and thevalve 123 are operated to introduce the liquid or gas (for example, ator near a constant flow rate) into the second inlet port 105 of themicrofluidic device 101. A pressure sensor 125 (such as a Sensotremesensor) is disposed within the supply line 127 between the valve 123 andthe second inlet port 105 in order to monitor the pressure of the testsample fluid in the supply line 127. The reservoir and pump 121 can bean electrically-controlled syringe pump, such as the ISCO 65D pump. Thesupply line 127 can include an in-line filter that removes particulatematter that could potentially clog the microchannel 111 of themicrofluidic device 101. The reservoir and pump 121, the valve 123, andthe supply line 127 can all operate at or near ambient temperature.

An optional pressure sensor 155 (such as a Sensotreme sensor) is fluidlyconnected between the mixing section 109 and the microchannel 111 inorder to monitor the pressure of fluid entering the microchannel 111.While the fluid pressure at the inlet of the microchannel 111 can bedirectly obtained using pressure sensor 155, such a pressure measurementmay also be obtained using a combination of pressure measurementsobtained using sensors 117 and 125. For example, instead of using sensor155 to measure the fluid pressure at the inlet of the microchannel 111,it is possible to approximate the inlet pressure using the average ofthe pressures obtained using sensors 117 and 125.

The outlet port 107 of the microfluidic device 101 is fluidly coupled toa collection chamber with a pump 129. The pump 129 can be controlled toapply a back pressure to the microchannel 107 to maintain a constantpressure at the inlet 109 of the microchannel 111. A pressure sensor 131(such as a Sensotreme sensor) is disposed within an outlet line 133between the outlet port 107 and the pump 129 in order to monitor thepressure of the fluid flowing in the outlet line 133.

Temperature sensors 137 and 139 are connected to microchannel 111.Sensor 137 is connected upstream of sensor 139. The temperature sensors137 and 139 can be used to monitor the temperature of the microchannel111 of the microfluidic device 101. The temperature sensors 137 and 139can be thermocouples, such as the Omega 5TC-TT-K 40-36 thermocoupleavailable from Omega Engineering Inc. of Laval, Quebec, Canada. Thetemperature-controlled cooling/heating surface 135 (FIG. 3) can be usedto control the temperature of specific sections of the microchannel 111instead of the entire microfluidic device 101. In this case, thetemperature sensors 137 and 139 can be used to measure the temperaturegradient along the sections of the microchannel 111 for control of thetemperature gradient by cooling/heating surface 135. Thetemperature-controlled cooling/heating surface 135 can be athermo-electric plate, such as a TEC model TC-36-25 RS485, availablefrom TE Technology, Inc. of Traverse City, Mich., USA.

A light source 141 and a camera 143 can be arranged to capturehigh-resolution images of the microchannel 111 of the microfluidicdevice 101 in order to detect the presence (or absence) of scale in themicrochannel 111 as described below.

The test apparatus 100 also includes a controller and/or computerprocessing system 145 that includes control logic that interfaces to theelectrically-controlled reservoir and pumps 113 and 121 and pump 129 viawired or wireless signal paths therebetween for control of the operationof the pumps 113, 121, and 129 that interfaces to theelectrically-controlled valves 115 and 123 via wired or wireless signalpaths therebetween for control of the operation of the valves 115 and123, that interfaces to the temperature-controlled cooling/heatingsurface 135 via wired or wireless signal paths therebetween in order toprovide for temperature control of the microfluidic device 101 (or themicrochannel 111 or portions thereof), that interfaces to the pressuresensors 117, 125, 131, and 155 via wired or wireless signal pathstherebetween for pressure measurements and recordation of such pressuremeasurements during operation of the test apparatus 100, and thatinterfaces to the temperature sensors 137 and 139 via wired or wirelesssignal paths therebetween for temperature measurements and recordationof such temperature measurements during operation of the test apparatus100. The controller and/or computer processing system 145 can alsointerface to the light source 141 and/or to the camera 143 via wired orwireless signal paths therebetween in order to capture high resolutionimages of the microchannel 111 and for recordation of such highresolution images and possibly display of such high resolution imagesduring operation of the test apparatus 100. The control logic of thecontroller and/or computer processing system 145 (which can be embodiedin software that is loaded from persistent memory and executed in thecomputing platform of the computer processing system 145) is configuredto control the different parts of the test apparatus 100 to carry out asequence of operations (workflow) that characterizes properties relatedto scale formation conditions (such as the scale formation temperatureand pressure) of the fluid that is introduced into the microchannel 111of the microfluidic device 101 as described below. The control logic canbe configured by user input or a testing script or other suitable datastructure, which is used to configure the controller or the computerprocessing system 145 in order to carry out control operations that arepart of the workflow as described herein. For example, the user input orthe testing script or other suitable data structure can specifyparameters (such as pressures, flow rates, temperatures, etc.) for suchcontrol operations of the workflow.

An embodiment of a workflow is illustrated in the flow chart of FIG. 5.At 500 the workflow begins and it is assumed that the reservoir and pump113 are filled with a sufficient quantity of the reservoir fluid samplethat contains dissolved scaling chemical species and the reservoir andpump 121 are filled with a sufficient quantity of liquid or gas. Theliquid or gas is a fluid to be injected into the petroleum reservoir oradded to the produced fluid to test compatibility with the reservoirfluid and/or its effectiveness in preventing or reducing scaleformation. For example, in a mitigation scenario, the type and relativeconcentration of the fluid can mimic a production environment in caseswhere a defined problem is arising. In a prevention scenario, prioranalysis of the reservoir fluids and conditions indicate the type andformation path of potential scaling. A bespoke fluid would be preparedand its effectiveness tested, most likely in an iterative process. Insome tests only the reservoir fluid sample from reservoir 113 is testedfor scale onset and no liquid or gas is injected by pump 121.

At 501 the test apparatus is initialized so that reservoir and pump 113and the corresponding valve 115 are controlled to introduce thereservoir fluid into the inlet port 103 of the microfluidic device 101while the reservoir and pump 121 and the corresponding valve 123 arecontrolled to introduce the liquid or gas into the inlet port 105 of themicrofluidic device 101. The pumping rates for the pumps 113 and 121 areconfigured such that the reservoir fluid and the liquid or gas aresupplied to the inlet ports 103 and 105 at a fixed proportion. That is,the flow rates for the reservoir fluid and the liquid or gas establishthe relative volume ratio of reservoir fluid to liquid or gas for thetest. The flow rates, and thus the resultant relative volume ratios ofreservoir fluid to liquid or gas, can be varied over multiple iterationsof the test as desired.

The reservoir fluid and liquid or gas supplied to the inlet ports 103and 105 are co-flowing fluids that flow to the mixing section 109 of themicrofluidic device 101. The reservoir fluid and the liquid or gas aremixed in the mixing section 109 and can exit the mixing section 109 as ahomogeneous fluid mixture. Due to the large surface-to-volume ratio ofthe microchannel 111, the flow of the mixture through the microchannel111 exhibits excellent mass transfer between the co-flowing fluids. Themixture exits the microchannel 111 and flows out the outlet port 107 ofthe microfluidic device 101 to the collection chamber and pump 129 viathe outlet line 133. The collection chamber and pump 129 is controlledto regulate a pressure of the mixture in the microchannel 111 to apressure that varies during operations in 505 and 507.

In 503, the temperature of the fluid flow through the microchannel 111is maintained at the reservoir temperature TR. Also, the inlet pressureP₄ of the fluid is initially maintained at or close to reservoirpressure PR and is regulated by the collection chamber and pump 129. Thereservoir pressure condition, at the reservoir temperature, is above thescale onset pressure.

The workflow carries out a sequence of operations in 505 and 507 thatvary the pressure of the mixture in the microchannel 111 in order todetermine properties related to the scale onset formation condition forthe mixture. In each of 505 and 507, the temperature of the mixture inthe microchannel 111 is controlled by maintaining the temperature of themicrochannel 111 via temperature control of the temperature-controlledcooling/heating surface 135. The temperature is maintained substantiallyconstant near the reservoir temperature, T_(R). As mentioned earlier,temperature equilibration in the microchannel 111 can be achievedquickly due to the availability of a relatively large surface area aswell as relatively small fluid volume of the microchannel 111. Duringthe operation of 505 and 507, pressures P₁, P₂, P₃, and P₄ are measured,respectively, by the pressure sensors 117, 125, 131, and 155 andrecorded by the computer processing system 145, and temperatures T₁ andT₂ are measured by the temperature sensors 137 and 139 and recorded bythe computer processing system 145. Such pressures and temperatures canalso be displayed on a graph relative to time for user evaluation, ifdesired. Such pressures and temperatures can also be stored in thememory system of the computer processing system 145 for automated dataanalysis if desired.

In 505, after a time period where the inlet pressure P₄ reaches a steadystate value, and the temperatures T₁ and T₂ reach steady state valuesnear the reservoir temperature TR, the flow of the mixture stops, valves115 and 123 are closed, and a fixed volume of the mixture is isolated inthe microchannel 111. The static pressure of the mixture in thetemperature-controlled section of the microchannel 111, as measured byP₃, is reduced in a discrete step, Pstep, by action of the collectionchamber and pump 129. The pressure step, Pstep, selected may be based onan approximation based on a theoretical model of scale formation orprior testing with the test apparatus. Also, the pressure step, Pstep,can be any numerical amount that is not related to modeling or empiricaltesting.

In 507, the microchannel 111 is visually monitored with the camera 143based on real time image analysis. FIG. 4 is a schematic representationof scale formed in the microchannel 111. The light source 141 and thecamera 143 can be used to capture one or more high resolution images ofthe microchannel 111 as part of the evaluation of 507. Such image(s) canbe displayed by the computer processing system 145 for evaluation by theoperator/user to ascertain if scale is present in the image(s).Precipitates of scale will crystalize on the microchannel 111 surfacesif the reduced pressure is below the scale onset pressure. If the visualcheck of the microchannel 111 does not indicate scale formation (NO at507), then the pressure is reduced again by Pstep at 505 and themicrochannel 111 is checked again at 507. If the visual check of themicrochannel 111 indicates that scale is formed (YES at 507), thentesting ends at 509. The pressure in the microchannel 111 during theiteration of 505 and 507 when scale is indicated (YES at 507)corresponds to the scale onset pressure at the temperature in themicrochannel 111, which in the example mentioned above, is at thereservoir temperature TR.

Note that the evaluation of 507 can be carried out by visualinterpretation of the images of the microchannel 111 by anoperator/user. For fully-automated and semi-automated implementations ofthe workflow, such evaluation can also involve image processing of theimage(s) of the microchannel 111 that is carried out by the computerprocessing system 145 in order to detect the presence (or absence) ofscale in the microchannel 111.

The workflow shown in FIG. 5 can be repeated multiple times usingdifferent Pstep values in order to determine the scale onset pressure.It will be appreciated that larger Pstep values may reduce the number ofiterations of 505 and 507 before determining the scale onset pressure,while smaller Pstep values may increase the number of iterations of 505and 507 before determining the scale onset pressure. Moreover, it willbe appreciated that larger Pstep values may yield a determination ofscale onset pressure that is less accurate than if smaller Pstep valuesare used. Thus, there may be a tradeoff in the workflow between durationof the testing and accuracy of the result in that smaller Pstepincrements may require more iterations and, thus, a longer workflow,while providing a more accurate determination of the scale onsetpressure, whereas larger Pstep increments may require less iterationsand, thus, a shorter workflow, while providing a less accurate (roughestimate) determination of the scale onset pressure. Also, the workflowcan be repeated multiple times with different volume ratios of thereservoir fluid to the liquid or gas in order to determine the scaleonset pressure of the fluid flow for the different ratios.

Another embodiment of a workflow is illustrated in the flow chart ofFIG. 6. At 602 the workflow begins and it is assumed that the reservoirand pump 113 are filled with a sufficient quantity of the reservoirfluid sample that contains dissolved scaling chemical species and thereservoir and pump 121 are filled with a sufficient quantity of theliquid or gas to be tested.

At 604 the test apparatus is initialized so that reservoir and pump 113and the corresponding valve 115 are controlled to introduce thereservoir fluid into the inlet port 103 of the microfluidic device 101while the reservoir and pump 121 and the corresponding valve 123 arecontrolled to introduce the liquid or gas into the inlet port 105 of themicrofluidic device 101. During the operation of 604, pressures P₁, P₂,P₃, and P₄ are measured, respectively, by the pressure sensors 117, 125,131, and 155 and recorded by the computer processing system 145, andtemperatures T₁ and T₂ are measured by the temperature sensors 137 and139 and recorded by the computer processing system 145. Such pressuresand temperatures can also be displayed on a graph relative to time foruser evaluation, if desired. Such pressures and temperatures can also bestored in the memory system of the computer processing system 145 forautomated data analysis if desired.

The pumping rates for the pumps 113 and 121 are configured such that thereservoir fluid and the liquid or gas are supplied to the inlet ports103 and 105 in a fixed proportion. That is, the flow rates for thereservoir fluid and the liquid or gas establish the relative volumeratio of reservoir fluid to liquid or gas for the test. The flow rates,and thus the resultant relative volume ratios of reservoir fluid toliquid or gas, can be varied over multiple iterations of the test asdesired. The reservoir fluid and liquid or gas that are supplied to theinlet ports 103 and 105 are co-flowing fluids that flow to the mixingsection 109 of the microfluidic device 101, which can form a homogeneousmixture. The resultant fluid mixture of the reservoir fluid and theliquid or gas flows through the microchannel 111 of the microfluidicdevice 101. Due to the large surface-to-volume ratio of the microchannel111, the flow through the microchannel 111 exhibits excellent masstransfer between the co-flowing fluids. The fluid mixture exits themicrochannel 111 and flows out the outlet port 107 of the microfluidicdevice 101 to the collection chamber and pump 129 via the outlet line133. The collection chamber and pump 129 are controlled to regulate(such as by applying a back pressure) the pressure of the mixture inmicrochannel 111.

At 606, the temperature of the mixture in the microchannel is regulatedto be at or close to the reservoir temperature T_(R), while the inletpressure P₄ of the mixture is regulated to be at or close to thereservoir pressure P_(R).

A sequence of operations in 608 and 610 checks whether scale is formedat various fluid temperatures while the fluid pressure of the mixture ismaintained at reservoir pressure. More specifically, the temperature ofthe fluid in the microchannel 111 is iteratively decreased in order todetermine properties related to the scale onset formation temperature atthe reservoir pressure for the fluid mixture in the microchannel 111. Ineach of the 608 and 610, the temperature of the bulk or mixed fluid flowin the microchannel 111 is controlled via temperature control of thetemperature-controlled cooling/heating surface 135. As mentionedearlier, temperature equilibration in the microchannel 111 can beachieved quickly due to the availability of large surface area as wellas small fluid volume of the microchannel 111.

In 608, after a time period where the inlet pressure P₄ reaches a steadystate value, and the temperatures T₁ and T₂ reach steady state valuesnear the reservoir temperature T_(R), the flow of the mixture stops,valves 115 and 123 are closed, and a resulting fixed volume of the fluidis isolated in the microchannel 111. The pressure of the fixed volume offluid in the microchannel 111 (as measured by any of pressure sensors117, 125, 131, and 155 since pressure is static) is maintained bycontrol of the collection chamber and pump 129. While the fluid pressurein microchannel 111 is maintained constant, the temperature of the fluidin microchannel 111 is decreased by a predetermined amount (Tstep) bycontrol of the temperature-controlled cooling/heating surface 135. Thetemperature step, Tstep, selected may be based on an approximationinformed by a theoretical model of scale formation or prior testing withthe test apparatus. Also, the temperature step, Tstep, can be anynumerical amount that is not related to modeling or empirical testing.

In 610, the microchannel 111 is visually monitored with the camera 143based on real time image analysis. FIG. 4 is a schematic representationof scale formed in the microchannel 111. The light source 141 and thecamera 143 can be used to capture one or more high resolution images ofthe microchannel 111 as part of the evaluation of 610. Such image(s) canbe displayed by the computer processing system 145 for evaluation by theoperator/user to ascertain if scale is present in the image(s).Precipitates of scale will crystalize on the microchannel 111 surfacesif the reduced temperature is below the scale onset temperature. If thevisual check of the microchannel 111 does not indicate scale formation(NO at 610), the temperature is reduced again by Tstep at 608 and themicrochannel 111 is checked again at 610. If the visual check of themicrochannel 111 indicates that scale is formed (YES at 610), testingends at 612. The temperature in microchannel 111, which can beapproximated to be the average of T₁ and T₂, during the iteration of 608and 610 when scale is indicated (YES at 610) corresponds to the scaleonset temperature at the pressure in the microchannel 111, which in theexample mentioned above, is at the reservoir pressure.

Note that the evaluation of 610 can be carried out by visualinterpretation of the images of the microchannel 111 by anoperator/user. For fully-automated and semi-automated implementations ofthe workflow, such evaluation can also involve image processing of theimage(s) of the microchannel 111 that is carried out by the computerprocessing system 145 in order to detect the presence (or absence) ofscale in microchannel 111.

Note that the workflow shown in FIG. 6 can be repeated multiple timesusing different Tstep values in order to determine the scale onsettemperature. It will be appreciated that larger Tstep values may reducethe number of iterations of 608 and 610 before determining the scaleonset temperature, while smaller Tstep values may increase the number ofiterations of 608 and 610 before determining the scale onsettemperature. Moreover, it will be appreciated that larger Tstep valuesmay yield a determination of scale onset temperature that is lessaccurate than if smaller Tstep values are used. Thus, there may be atradeoff in the workflow between duration of the testing and accuracy ofthe result in that smaller Tstep increments may require more iterationsand, thus, a longer workflow, while providing a more accuratedetermination of the scale onset temperature, whereas larger Tstepincrements may require fewer iterations and, thus, a shorter workflow,while providing a less accurate (rough estimate) determination of thescale onset temperature. Also, the workflow can be repeated multipletimes with different volume ratios of the reservoir fluid to the liquidor gas in order to determine the scale onset temperature of the fluidflow for the different ratios.

In the workflows described with respect to FIGS. 5 and 6, the flow ofthe fluid mixture in the microchannel 111 is static while the respectivetest parameter (i.e., pressure or temperature) is iteratively changed.It will be appreciated, however, that in alternate workflows the fluidmixture introduced into the microchannel is flowing at a predeterminedflow rate while the respective test parameter is iteratively changed.

Another embodiment of a workflow is illustrated in the flow chart ofFIG. 7. The workflow begins at 700. It is assumed that the reservoir andpump 113 are filled with a sufficient quantity of reservoir fluid thatcontains dissolved scaling chemical species and the reservoir and pump121 are filled with a sufficient quantity of liquid or gas to be tested.At 701 the reservoir and pump 113 and the corresponding valve 115 arecontrolled to introduce reservoir fluid into the inlet port 103 of themicrofluidic device 101 while the reservoir and pump 121 and thecorresponding valve 123 are controlled to introduce liquid or gas intothe inlet port 105 of the microfluidic device 101. The pumping rates forthe pumps 113 and 121 are configured such that the reservoir fluid andliquid or gas are supplied to the inlet ports 103 and 105 at constantflow rates. The flow rates for the reservoir fluid and liquid or gasestablish the relative volume ratio of reservoir fluid to liquid or gasfor the test. The flow rates and thus the resultant relative volumeratios of reservoir fluid to liquid or gas can be varied over multipleiterations of the test as desired. The reservoir fluid and liquid or gasthat are supplied to the inlet ports 103 and 105 flow to the mixingsection 109 of the microfluidic device 101, where the fluids mix to forma fluid mixture that exits mixing section 109. Due to the largesurface-to-volume ratio of the microchannel 111, the mixture flowingthrough the microchannel 111 exhibits excellent mass transfer betweenthe co-flowing fluids. The mixture exits the microchannel 111 and flowsout the outlet port 107 of the microfluidic device 101 to the collectionchamber and pump 129 via the outlet line 133.

Concurrent with the operations of 701, the workflow carries out asequence of operations in 705 and 707 that vary the volumetric flow rateof the fluid flow through the microchannel 111 in order to determineproperties related to the scale onset formation condition for the flowthrough the microchannel 111. In each of 705 and 707, the temperature ofthe mixture through the microchannel 111 is maintained at the reservoirtemperature TR via temperature control of the temperature-controlledcooling/heating surface 135. As mentioned earlier, temperatureequilibration in the microchannel 111 can be achieved quickly due to theavailability of large surface area as well as small fluid volume of themicrochannel 111. During the operation of 705 and 707, pressures P₁, P₂,P₃, and P₄ are measured by the pressure sensors 117, 125, 131, and 155and recorded by the computer processing system 145, and temperatures T₁and T₂ are measured by the temperature sensors 137 and 139 and recordedby the computer processing system 145. Such pressures and temperaturescan also be displayed on a graph relative to time for user evaluation,if desired. Such pressures and temperatures can also be stored in thememory system of the computer processing system 145 for automated dataanalysis if desired.

In 703, the temperature of the mixture through the microchannel 111 isregulated such that it is maintained at the reservoir temperature T_(R).The flow rate of the mixture is initially set high to establish a highinlet pressure P₄ close to reservoir pressure, where the scalingchemical species is dissolved. Thus, the high average pressure value atthe reservoir temperature T_(R) is well above the scale onset pressurefor the constant flow conditions in the microchannel 111. After a timeperiod where the inlet pressure P₄ reaches a steady state value near thereservoir pressure P_(R), and the temperatures T₁ and T₂ reach steadystate values near the reservoir temperature T_(R), at 705, the flow rateof the mixture is reduced in stepwise fashion. The mixture flow rate isreduced by a step, Qstep, by reducing the respective flow rates of thereservoir fluid and the liquid or gas supplied to the inlet ports 103and 105 at the mixing ratio set for the testing.

In a fully developed laminar flow through a circular channel, thepressure drop for driving the liquid at a specified flow rate can becalculated by using the Hagen-Poiseuille equation as follows:

$\begin{matrix}{{\Delta \; p} = \frac{128\mu_{L}{QL}}{\pi \; D_{h}^{4}}} & (1)\end{matrix}$

-   -   where μL is the liquid viscosity,    -   Q is the average volumetric flow rate through the channel,    -   L is the total channel length, and    -   D_(h) (=4×cross-section/wetted perimeter) is the hydraulic        diameter of the channel.

For a constant flow in a fixed-length channel, the pressure drop scaleslinearly with viscosity. However, the channel diameter can have a largerinfluence (fourth power of D_(h)) on the pressure drop. Therefore, asmall variation in a channel cross-section or viscosity can be easilydetected by monitoring the pressure drop. It should be noted that thesurface-to-volume ratio varies as D_(h) ⁻¹. Thus, the pressure droprequired for a constant flow in the microchannel 111 is expected to beconsiderably higher (based on Eq. 1) when scale forms inside themicrochannel 111 than in the case of simple fluid flow. The flow of thefluid carrying precipitated scale is analogous to the flow of particlesuspensions, where the effective viscosity in the flow increases due tothe presence of solid particles. Additionally, the deposition of scaleon the internal surface of the microchannel 111 also reduces thehydraulic diameter. Both of these two effects contribute to an increasein the pressure drop in the microchannel 111 to maintain the volumetricflow.

Equation (1) can also be rewritten as follows:

Δp=KQ   (2)

-   -   where K is a flow characteristic represented by:

$\begin{matrix}{K = \frac{128L\; \mu_{L}}{\pi \; D_{h}^{4}}} & (3)\end{matrix}$

-   -   where μ_(L) is the liquid viscosity,    -   L is the total channel length, and    -   D_(h) (=4×cross-section/wetted perimeter) is the hydraulic        diameter of the channel.        Thus, the inlet pressure P₄ can be represented as:

P ₄ =P ₃ +KQ   (4)

When the flow characteristic K is constant, the pressure drop, and thusthe inlet pressure P₄, vary linearly with Q. K is assumed to be constantwhen scale has not formed and the viscosity and hydraulic diameter arenot affected by scale formation. Therefore, in the absence of scaleformation occurring, the pressure drop and the inlet pressure P₄ areexpected to vary linearly with the flow characteristic K. Specifically,if the inlet pressure P₄ is plotted against flow rate Q while K isconstant, the inlet pressure P₄ would be represented by a straight linehaving a slope K and offset of P₃. However, if scale begins to form asthe volumetric flow rate is changed by Qstep, then the value of the flowcharacteristic K would begin to deviate from the value of K before scalebegan to form. Such a change in the value of the flow characteristic Kmay be attributed to a change in viscosity of the fluid due to scaleprecipitate formation and/or a change in the hydraulic diameter due toscale formation on the microchannel. Thus, when scale begins to form inthe flowing fluid and/or on the microchannel 111, the pressure P₄ wouldnot lie on the straight line mentioned above in the case where the flowcharacteristic K is constant. Therefore, it is possible to denote thescale onset pressure P₄ by comparing an expected pressure drop (assuminga linear relationship between pressure drop and volumetric flow ratewhen K is constant) for each Qstep increment with the actual pressuredrop measured for each Qstep increment. When the actual pressure dropmeasured deviates significantly from the expected pressure drop, thedeviation can be attributed to scale formation and the inlet pressure P₄at that formation condition can be taken to correspond to the scaleonset pressure.

Specifically, the pressure difference P₄-P₃ at 707 is compared to theexpected pressure difference P₄-P₃ under the steady state conditions asrecorded in 703. Such comparisons provide an indication of scaleformation in the microchannel 111. For example, if the pressuredifference P₄-P₃ varies non-linearly with the volumetric flow rate(i.e., the pressure drop is larger than the pressure drop that would beexpected after Qstep assuming no change in viscosity and hydraulicdiameter), the non-linearity can be an indication that the viscosityand/or the hydraulic diameter D_(h) has changed, which in turn can betaken to indicate that scale has formed causing the additional increasein the pressure differentials indicate higher flow resistance in themicrochannel 111 caused by scale formation.

In 707, the pressure drop in microchannel 111 is compared to theexpected pressure drop across the microchannel 111 based upon the flowcharacteristic obtained when scale is not precipitated from the mixture.If the pressure drop increased abruptly, then it is an indication thatthe scale onset pressure (corresponding to the reduced flow rate) hasbeen reached (YES at 707). The magnitude of the abrupt change inpressure drop depends on the characteristics of the fluid sample, suchas the amount and type of scale formed at onset, used in the test.However, in microchannels with small hydraulic diameter D_(h), thechange in pressure drop will be noticeably different after the formationof scale. If the scale onset pressure has been reached, then the inletpressure P₄ at the flow rate set in 707 is recorded in the computerprocessing system 145 as the scale onset pressure and the workflow endsat 709. However, if the pressure drop did not increase abruptly, then itis an indication that the scale onset pressure has not been reached (NOat 707) and, therefore, the workflow proceeds back to 705 where the bulkflow rate of the mixed flow is reduced again in stepwise fashion.

Note that the evaluation of 707 can be carried out by visualinterpretation of the pressure data and/or images of the microchannel111 by the operator/user. For fully-automated and semi-automatedimplementations of the workflow, such evaluation can also involve signalprocessing of the pressure data for P₁, P₂, P₃, and P₄ that is carriedout by the computer processing system 145 in order to derive anindication of scale formation and/or can involve image processing of theimage(s) of the microchannel 111 that is carried out by the computerprocessing system 145 in order to detect the presence (or absence) ofscale in the microchannel 111.

The workflow shown in FIG. 7 can be repeated multiple times usingdifferent Qstep values in order to determine the scale onset pressure.It will be appreciated that larger Qstep values may reduce the number ofiterations of 705 and 707 before determining the scale onset pressure,while smaller Qstep values may increase the number of iterations of 705and 707 before determining the scale onset pressure. Moreover, it willbe appreciated that larger Qstep values may yield a determination ofscale onset pressure that is less accurate than if smaller Qstep valuesare used. Thus, there may be a tradeoff in the workflow between durationof the testing and accuracy of the result in that smaller Qstepincrements may require more iterations and, thus, a longer workflow,while providing a more accurate determination of the scale onsetpressure, whereas larger Qstep increments may require less iterationsand, thus, a shorter workflow, while providing a less accurate (roughestimate) determination of the scale onset pressure. Also, the workflowcan be repeated multiple times with different volume ratios of thereservoir fluid and liquid or gas to be tested in order to determine thescale onset pressure of the fluid flow for the different reservoirfluid-test fluid volume ratios.

The test apparatus 100 (and the workflows of FIGS. 5, 6, and 7) asdescribed herein can readily be adapted as depicted in FIG. 8 tocharacterize properties of scale formation for a reservoir fluid sample.FIG. 8 shows the test apparatus 100 of FIG. 1 modified with the additionof an additional reservoir and pump 150, a corresponding valve 151, anda pressure sensor 157, which are connected to the apparatus 100 betweenthe mixing section 109 and the microchannel 111. The test apparatus 100also includes the controller and/or computer processing system 145 thatincludes control logic that interfaces to the electrically-controlledreservoir and pumps 113, 121, and 150 via wired or wireless signal pathstherebetween for control of the operation of the pumps 113, 121, and150, that interfaces to the electrically-controlled valves 115, 123, and151 via wired or wireless signal paths therebetween for control of theoperation of the valves 115, 123, and 151, that interfaces to thetemperature-controlled cooling/heating surface 135 via wired or wirelesssignal paths therebetween in order to provide for temperature control ofthe microfluidic device 101 (or the microchannel 111 or portionsthereof), that interfaces to the pressure sensors 117, 125, 131, 155,and 157 via wired or wireless signal paths therebetween for pressuremeasurements and recordation of such pressure measurements duringoperation of the test apparatus 100, and that interfaces to thetemperature sensors 137 and 139 via wired or wireless signal pathstherebetween for temperature measurements and recordation of suchtemperature measurements during operation of the test apparatus 100. Thecontroller and/or computer processing system 145 can also interface tothe light source 141 and/or to the camera 143 via wired or wirelesssignal paths therebetween in order to capture high resolution images ofthe microchannel 111 and recordation of such high resolution images andpossibly display of such high resolution images during operation of thetest apparatus 100. The control logic of the controller and/or computerprocessing system 145 (which can be embodied in software that is loadedfrom persistent memory and executed in the computing platform of thecomputer processing system 145) is configured to control the differentparts of the test apparatus 100 to carry out a sequence of operations(workflow) that characterizes properties related to scale formationcondition (such as scale formation temperature and pressure) of thefluid that is introduced into the microchannel 111 of the microfluidicdevice 101 as described hereinabove. The control logic can be configuredby user input or a testing script or other suitable data structure,which is used to configure the controller or the computer processingsystem 145 in order to carry out control operations that are part of theworkflow as described herein. For example, the user input or the testingscript or other suitable data structure can specify parameters (such aspressures, flow rates, temperatures, etc.) for such control operationsof the workflow.

The remainder of the test apparatus 100 described above in connectionwith FIG. 1 is constructed and operates as described hereinabove andwill not be repeated for the sake of brevity. The reservoir and pump 150can optionally be filled with a sufficient quantity of an additive, suchas a scale inhibitor (that inhibits formation of scale when mixed withthe reservoir fluid). In this case, the reservoir and pump 113 and thecorresponding valve 115 are controlled to introduce the reservoir fluidinto the inlet port 103 of the microfluidic device 101, the reservoirand pump 121 and the corresponding valve 123 are optionally controlledto introduce a fluid (liquid or gas) into the inlet port 105 of themicrofluidic device 101, and the reservoir and pump 150 and thecorresponding valve 151 are optionally controlled to introduce theadditive into the inlet port 105 of the microfluidic device 101. Thus,the construction of test apparatus 100 permits at least three fluidsfrom the respective reservoir and pumps 113, 121, and 150 to be premixedaccording to a predetermined mixture ratio before entering themicrochannel 111. The pumping rates for the pumps 113, 121, and 150 areconfigured such that the respective fluids are supplied at constant flowrates.

The workflow processes described hereinabove with respect to FIGS. 5, 6,and 7 can also be carried out using the modified test apparatus 100shown in FIG. 8 to determine the scale onset pressure for variousmixtures of reservoir fluid, fluids (such as liquid or gas), and scaleinhibitors.

For example, the flow rates and, thus, the resultant relative volumeratios of reservoir fluid and scale inhibitor can be varied overmultiple iterations of the test in order to study scale onset pressurefor different flow pressures and/or scale inhibitor concentrations asdesired. Similarly, the multiple iterations of the tests can be repeatedwith different scale inhibitors in order to study the effects ofdifferent scale inhibitors on the particular reservoir fluid sample atdifferent pressures and/or scale inhibitor concentrations, as desired.The results of such test workflow operations can be used to optimize astrategy for reservoir fluid production and/or transportation thatminimizes the formation of scale during these processes.

The test apparatus and the workflow as described herein may provide someadvantages. The apparatus and workflow described herein can rapidlydetermine scale onset conditions. Also, the test apparatus and workfloware suitable for a wellsite environment. The apparatus and workflowexhibit excellent repeatability in the determination of scale onsetconditions. The data obtained using the apparatus and workflow describedherein is high quality data, and is comparable to conventionalpressure-volume-temperature (PVT) laboratory measurements. Additionally,the apparatus and workflow described herein do not require large samplevolumes and can be automated to a large extent, making them somewhatoperator independent. Moreover, the apparatus and workflow describedherein are suitable for testing and screening additives and scaleinhibitors.

There have been described and illustrated herein several embodiments oftest apparatus and method that employs a microfluidic device tocharacterize properties of scale formation of a fluid. While particularembodiments of the invention have been described, it is not intendedthat the invention be limited thereto, as it is intended that theinvention be as broad in scope as the art will allow and that thespecification be read likewise. It will therefore be appreciated bythose skilled in the art that yet other modifications could be made tothe provided invention without deviating from its scope as claimed.

What is claimed is:
 1. A test method for characterizing properties of afluid, comprising: providing a microfluidic device having at least aninlet port, an outlet port, and a microchannel as part of a fluid pathbetween the first inlet port and the outlet port; generating a flow ofthe fluid through the microchannel at a variable flow rate; maintaininga temperature of the fluid flowing through the microchannel; measuringand recording a pressure difference of the fluid across the microchanneland an average pressure of the fluid between an inlet and an outlet ofthe microchannel; evaluating or analyzing the pressure difference whilethe flow rate is varied to determine whether the fluid in themicrochannel flowing through the microchannel exhibits characteristicsindicative of the presence of scale formation.
 2. A test methodaccording to claim 1, wherein evaluating or analyzing the pressuredifference includes determining if the pressure difference varieslinearly with the flow rate, wherein, if it is determined that thepressure difference varies linearly with the flow rate, then it isfurther determined that the fluid in the microchannel does not exhibitcharacteristics indicative of the presence of scale formation, and if itis determined that the pressure difference varies non-linearly with theflow rate, then it is further determined that the fluid in themicrochannel does exhibit characteristics indicative of the presence ofscale formation.
 3. A test method according to claim 2, furthercomprising identifying a scale onset pressure where scale begins to formas the average pressure recorded at a transition point where thepressure difference transitions between varying linearly andnon-linearly with the flow rate and between varying non-linearly andlinearly with the flow rate.
 4. A test method according to claim 3,wherein the fluid includes at least one of a reservoir fluid, a scaleinhibitor, water, and a gas.
 5. A test method for characterizingproperties of a fluid, comprising: providing a microfluidic devicehaving at least an inlet port, an outlet port, and a microchannel aspart of a fluid path between the first inlet port and the outlet port;introducing the fluid into the microchannel; maintaining a constantpressure to the fluid in the microchannel; measuring and recordingpressure and temperature of the fluid in the microchannel; adjusting thetemperature of the fluid in the microchannel; evaluating the fluid whilethe temperature of the fluid is adjusted; characterizing properties ofthe fluid in the microchannel based on the evaluation of the fluid.
 6. Atest method according to claim 5, wherein the properties of the fluidrelate to the scale onset formation condition of the fluid at theapplied pressure and a scale onset temperature.
 7. A test methodaccording to claim 6, further comprising repeating adjusting thetemperature of the fluid in the microchannel, evaluating the fluid whilethe temperature of the fluid is adjusted, and characterizing propertiesof the fluid in the microchannel based on the evaluation of the fluiduntil the scale onset formation condition occurs.
 8. A test methodaccording to claim 7, further comprising capturing images of the fluidin the microchannel.
 9. A test method according to claim 8, whereinevaluating the fluid includes analyzing the captured images in order todetermine whether such images include information that indicates thepresence of scale formation in the fluid in the microchannel.
 10. A testmethod according to claim 9, wherein the fluid introduced into themicrochannel includes at least one of a reservoir fluid, a scaleinhibitor, water, and a gas.
 11. A test apparatus for characterizingproperties of a fluid, comprising: a microfluidic device having at leastan inlet port, an outlet port, and a microchannel as part of a fluidpath between the first inlet port and the outlet port; atemperature-controlled surface that is thermally-coupled to themicrofluidic device and configured to maintain a temperature of themicrochannel of the microfluidic device; at least one temperature sensorfor measuring a temperature characteristic of the microchannel of themicrofluidic device; and means for introducing the fluid into themicrochannel; a pressure sensor configured to measure pressure of thefluid in the microchannel; means for adjusting the pressure of the fluidin the microchannel while the temperature characteristic is maintainedfor evaluation of the fluid while the pressure is adjusted tocharacterize properties of the fluid in the microchannel based on theevaluation of the fluid.
 12. A test apparatus according to claim 11,further comprising a light source and camera configured to captureimages of the microchannel of the microfluidic device and fluid in themicrochannel.
 13. A test apparatus according to claim 12, furthercomprising: means for evaluating or analyzing the images captured by thecamera in order to determine whether such images include informationthat indicates the presence of scale formation in the fluid that flowsthrough the microchannel of the microfluidic device at a respectiveadjusted pressure; and wherein the means for adjusting the fluidpressure is constructed to iteratively adjust the fluid pressure and themeans for evaluating or analyzing the images is constructed toiteratively evaluate the images captured by the camera of the fluid inthe microchannel corresponding to each iterative adjustment of the fluidpressure.
 14. A test apparatus for characterizing properties of a fluid,comprising: a microfluidic device having at least an inlet port, anoutlet port, and a microchannel as part of a fluid path between thefirst inlet port and the outlet port; means for generating a flow of thefluid through the microchannel at a variable flow rate; atemperature-controlled surface that is thermally-coupled to themicrofluidic device and configured to maintain a temperature of themicrochannel of the microfluidic device; an inlet pressure sensorconfigured to measure an inlet pressure of the fluid at the inlet of themicrochannel; an outlet pressure sensor configured to measure an outletpressure of the fluid at the outlet of the microchannel; measurement andrecording means for measuring and recording a pressure differencebetween the inlet and outlet pressures and measuring and recording anaverage of the inlet and outlet pressures; means for evaluating oranalyzing the pressure difference while the flow rate is varied todetermine whether the fluid in the microchannel flowing through themicrochannel exhibits characteristics indicative of the presence ofscale formation.
 15. A test apparatus according to claim 14, wherein themeans for evaluating or analyzing the pressure difference determine ifthe pressure difference varies linearly with the flow rate, wherein, ifit is determined that the pressure difference varies linearly with theflow rate, then it is further determined that the fluid in themicrochannel does not exhibit characteristics indicative of the presenceof scale formation, and if it is determined that the pressure differencevaries non-linearly with the flow rate, then it is further determinedthat the fluid in the microchannel does exhibit characteristicsindicative of the presence of scale formation.
 16. A test methodaccording to claim 15, wherein the means for evaluating or analyzing thepressure difference identify a scale onset pressure, where scale beginsto form, as the average pressure recorded at a transition point wherethe pressure difference transitions between varying linearly andnon-linearly with the flow rate and between varying non-linearly andlinearly with the flow rate.
 17. A test apparatus for characterizingproperties of a fluid, comprising: a microfluidic device having at leastan inlet port, an outlet port, and a microchannel as part of a fluidpath between the first inlet port and the outlet port; means forintroducing the fluid into the microchannel; means for maintaining aconstant pressure of the fluid in the microchannel; atemperature-controlled surface that is thermally-coupled to themicrofluidic device and configured to adjust a temperature of themicrochannel of the microfluidic device; a pressure sensor configured tomeasure the pressure of fluid in the microchannel; a temperature sensorconfigured to measure the temperature of fluid in the microchannel; andmeans for evaluating the fluid while the temperature of the fluid isadjusted.
 18. A test apparatus according to claim 17, wherein theproperties of the fluid relate to the scale onset formation condition ofthe fluid at the applied pressure and a scale onset temperature.
 19. Atest apparatus according to claim 18, wherein the means for evaluatingthe fluid include a light source and camera configured to capture imagesof the microchannel of the microfluidic device and fluid in themicrochannel.
 20. A test method according to claim 19, furthercomprising means for characterizing properties of the fluid in themicrochannel based on the evaluation of the fluid, the means constructedto determine, responsive to analyzing the captured images, whether theimages include information that indicates the presence of scaleformation in the fluid in the microchannel.